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Salt extraction process : ウィキペディア英語版
Salt extraction process

The salt extraction process is an electrolytic method which may be used to extract valuable metals from slag, low-grade ores, or other materials by using molten salts. This method was developed by S. Seetharaman, O. Grinder, L. Teng and X. Ge at the Royal Institute of Technology in Sweden as part of a large Steel Eco-Cycle Project in 2005.
== Description==
In the first step of this process, the slag or other raw materials containing metal values of interest, e.g. chromium, is dissolved into the molten salt phase at a suitable temperature. It is important to find a suitable flux to achieve the dissolution of oxides. According to the Fajans' rules, AlCl3, as a covalent metal chloride, is able to release chloride ions, which then can effectively break the chemical bonds between metal and oxygen atoms, leading to the formation of corresponding soluble metal chlorides and capture of oxygen in Al2O3·AlCl3 was proved indeed to be a powerful fluxing agent in this regard.〔Salt Extraction AB. A process for chlorinating resources containing recoverable metals. International Publication Date (19.11.2009). International Application Number: PCT/SE2009/050538. International Publication Number: PCT: WO 2009/139 715 A1 (World Patent)〕
In the second step, the salt phase is subjected to electrolysis in order to recover the metal of interest as a cathode deposit. It is interesting to note that the salt melt used for extraction can be recycled. The metals can be selectively electrodeposited from the salt melt. There is also the option of aqueous processing of the salt phase containing the metal values. The process can design to be continuous by combining the two steps. The anode off-gas from electrolysis, Cl2 can be reused for accentuating the dissolution of the raw materials. On the other hand, the residue after processing, which consists essentially of Al2O3, can safely be used for landfill, building construction or as a raw material for the refractory industry.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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